| Hydrogen, the first element in the periodic table, is a | | | | aggravated by overexposure to hydrogen. When |
| colorless, odorless and insipid gas, formed by its | | | | inhaled a harmful concentration of this gas in the air |
| diatomic molecules, in normal conditions. The | | | | will be reached very quickly. |
| hydrogen atom is formed by a nucleus with one unit | | | | Heating may cause violent combustion or explosion |
| of positive charge and one electron. It’s one of | | | | as the gas reacts violently with air, oxygen, halogens |
| the main compounds of water and of all organic | | | | and strong oxidants causing fire and explosion hazard. |
| matter, and it’s widely spread not only in the | | | | Metal catalysts greatly enhance these reactions. High |
| Earth but also in the entire Universe. There are three | | | | concentrations in the air cause a deficiency of |
| hydrogen isotopes: protium, mass 1, found in more | | | | oxygen with the risk of unconsciousness or death. |
| than 99,985% of the natural element; deuterium, | | | | We must check oxygen content before entering a |
| mass 2, found in nature in 0.015% approximately, and | | | | suspected area as there is no odor warning if toxic |
| tritium, mass 3, which appears in small quantities in | | | | concentrations are present. We may measure |
| nature, but can be artificially produced by various | | | | hydrogen concentrations with suitable gas detector |
| nuclear reactions. | | | | (a normal flammable gas detector is not suited for |
| | | | | the purpose). In case of inhalation problem we should |
| Hydrogen forms 0.15 % of the earth's crust and it is | | | | shut off its supply. In case it not possible and there |
| the major constituent of water. 0.5 ppm of hydrogen | | | | seems no risk to surroundings, let the fire burn itself |
| H2 and variable proportions as water vapor are | | | | out; in other cases extinguish with water spray, |
| present in the atmosphere. Hydrogen is also a major | | | | powder, carbon dioxide. In case of fire we should |
| component of biomass, constituting the 14% by | | | | keep its cylinder cool by spraying with water. One |
| weight. Hydrogen occurs naturally in the atmosphere. | | | | must combat fire from a sheltered position and rush |
| The gas will be dissipated rapidly in well-ventilated | | | | for medical aid and advice in case of all inhalation and |
| areas. Any Effect of hydrogen on plants or animals | | | | contact cases. |
| would be related to oxygen deficient environments. | | | | Deuterium |
| No adverse effect is anticipated to occur to plant life, | | | | Deuterium is the stable, nonradioactive isotope of |
| except for frost produced in the presence of rapidly | | | | hydrogen, commonly called heavy hydrogen because |
| expanding gases. No evidence is currently available on | | | | its atomic weight is approximately doubles that of |
| the effect of hydrogen on aquatic life. | | | | ordinary hydrogen, but it has identical chemical |
| | | | | properties. Deuterium has about twice the atomic |
| Hydrogen is the most flammable of all the known | | | | weight of normal hydrogen because its nucleus |
| substances. It is slightly more soluble in organic | | | | contains a proton and a neutron, instead of just a |
| solvents than in water. Many metals absorb hydrogen. | | | | proton. Hydrogen as it occurs in nature contains |
| Hydrogen absorption by steel can result in brittle | | | | approximately 0.02 percent of deuterium that was |
| steel, which leads to faults in the chemical process | | | | the first isotope to be separated in a pure form from |
| equipments. At normal temperature hydrogen is a not | | | | an element. Several methods have been used to |
| very reactive substance, unless it has been activated | | | | separate the isotope from natural hydrogen. The two |
| somehow; for instance, by an appropriate catalyser. | | | | processes that have been most successful have |
| At high temperatures it’s highly reactive. | | | | been fractional distillation of water and a catalytic |
| Although in general it’s diatomic, molecular | | | | exchange process between hydrogen and water. In |
| hydrogen dissociates into free atoms at high | | | | the latter system, when water and hydrogen are |
| temperatures. Atomic hydrogen is a powerful | | | | brought together in the presence of a suitable |
| reductive agent, even at ambient temperature. It | | | | catalyst, about three times as much deuterium |
| reacts with the oxides and chlorides of many metals | | | | appears in the water as in hydrogen. Deuterium has |
| to produce free metals. It reduces some salts to | | | | also been concentrated by electrolysis, centrifuging, |
| their metallic state and reacts with a number of | | | | and fractional distillation of liquid hydrogen. The nuclei |
| elements, both metals and non-metals to produce | | | | of deuterium atoms, called deuterons, are much used |
| their hydrides. Atomic hydrogen reacts with organic | | | | in research in physics because they can be readily |
| compounds to form a complex mixture of products. | | | | accelerated by cyclotrons and similar machines and |
| The heat released when the hydrogen atoms | | | | used as “atomic bullets” to transform an |
| recombine to form the hydrogen molecules is used | | | | atom of one element into another element. |
| to obtain high temperatures in atomic hydrogen | | | | Deuterium also has important uses in biological |
| welding. | | | | research as a tracer element for studying problems |
| | | | | of metabolism. |
| The most important use of hydrogen is the synthesis | | | | Regular hydrogen and deuterium are not normally |
| of ammonia. The use of hydrogen is extending | | | | metallic, meaning they are not shiny or malleable. |
| quickly in fuel refinement, like the breaking down by | | | | Scientists have used pressure and heat, however, to |
| hydrogen (hydrocracking), and in sulphur elimination. | | | | force deuterium to act like a metal, making it shinier |
| Huge quantities of hydrogen are consumed in the | | | | and easier to compress. Studying deuterium in |
| catalytic hydrogenation of unsaturated vegetable oils | | | | compressed and highly hot conditions can help |
| to obtain solid fat. Hydrogenation is used in the | | | | scientists understand how hydrogen behaves in the |
| manufacture of organic chemical products. Huge | | | | hot, heavily pressurized interiors of planets and in the |
| quantities of hydrogen are used as rocket fuels, in | | | | interiors of stars. The use of heavy water as a |
| combination with oxygen or flour, and as a rocket | | | | moderator in atomic piles has been suggested and |
| propellant propelled by nuclear energy. Hydrogen can | | | | Deuterium, either in deuterium oxide or in lithium |
| be burned in internal combustion engines. Hydrogen | | | | deuteride, and tritium are essential components of |
| fuel cells are being looked into as a way to provide | | | | nuclear fusion weapons, or hydrogen bombs. |
| power and research is being conducted on hydrogen | | | | |
| as a possible major future fuel. For instance it can be | | | | Tritium |
| converted to and from electricity from bio-fuels, | | | | Tritium is the radioactive hydrogen isotope of atomic |
| from and into natural gas and diesel fuel, theoretically | | | | mass 3 and symbol 1H3 or T. The nucleus of a tritium |
| with no emissions of either CO2 or toxic chemicals. | | | | atom consists of a proton and two neutrons. It |
| | | | | undergoes decay by beta emission to give a helium |
| As hydrogen is extremely flammable, its many | | | | nucleus of mass 3; it has a half-life of 12.26 years. |
| reactions may cause fire or explosion. As the gas | | | | Tritium is produced in a number of ways, including the |
| mixes well with air, explosive mixtures are easily | | | | bombardment of deuterium compounds with |
| formed. Moreover the gas is lighter than air. The gas | | | | high-energy deuterons and by the absorption of |
| can be absorbed into the body by inhalation and high | | | | neutrons by the lithium isotope of mass 6. Some |
| concentrations can cause an oxygen-deficient | | | | tritium is produced in the upper levels of the |
| environment. Individuals breathing such an | | | | atmosphere by the bombardment of nitrogen with |
| atmosphere may experience symptoms which include | | | | energetic neutrons produced by cosmic rays; |
| headaches, ringing in ears, dizziness, drowsiness, | | | | rainwater is usually found to contain minute amounts |
| unconsciousness, nausea, vomiting and depression of | | | | of tritium. The enormous amount of energy released |
| all the senses. The skin of a victim may have a blue | | | | when tritons react with deuterons in the so-called |
| color. Under some circumstances, death may occur. | | | | nuclear-fusion process makes tritium an important |
| Hydrogen is not expected to cause mutagenicity, | | | | constituent of hydrogen bombs. Tritium is also used |
| embryotoxicity, teratogenicity or reproductive | | | | as a tracer in chemical and biochemical research. |
| toxicity. Pre-existing respiratory conditions may be | | | | |